Entropy production in ac-calorimetry

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Entropy production in ac-calorimetry

In calorimetry and particularly in heat capacity measurements, different characteristic relaxation time constants may perturb the experiment which cannot be considered at thermodynamic equilibrium. In this case, thermodynamics of irreversible processes has to be taken into account and the calorimetric measurements must be considered as dynamic. In a temperature modulated experiment, such as ac-...

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ژورنال

عنوان ژورنال: Thermochimica Acta

سال: 2007

ISSN: 0040-6031

DOI: 10.1016/j.tca.2007.05.022